Supercritical CO2 has been looked at a lot for the Brayton cycle which can get 50% efficiency compared to steam that generally caps out around 34%
The US and china both published studies talking about a brayton turbine but to my knowledge no commercial plants running off of it have been built yet




They would melt, but we do also have gamma voltaics which can use the gamma radiation from fission and fusion to generate electricity they just have an atrocious efficiency